HELIUM WAS FOUND ON THE SUN TWENTY-SEVEN YEARS BEFORE IT WAS FOUND ON EARTH
On 18 August 1868, during a total solar eclipse observed from Guntur in India, Jules Janssen saw a bright yellow line in the light of the solar chromosphere. In October of the same year Norman Lockyer found the same line in the spectrum of the Sun. The yellow lines of sodium were familiar to everyone and were labelled D₁ and D₂; this one stood beside them, matched neither, and was labelled D₃. Lockyer concluded that it belonged to a substance unknown on Earth and named it after Helios. The substance itself was not isolated until 1895, when William Ramsay drew the gas out of the mineral cleveite and saw the same yellow line.
The claim rested on a distance of less than one and a half nanometres, and it held, because the position of a line is a difference between two energy levels of the atom rather than a property of the sample: a spectrum does not depend on how much of the substance was taken, nor on how many million kilometres away it shines.